CL 203

Chemical Engineering Thermodynamics

3-1-0-8

 

Syllabus:

Thermodynamic systems, variables and processes; Equilibrium and phase rule; Equations of State; Volumetric Properties of Mixtures; Concept of internal energy and enthalpy; The First Law of Thermodynamics and its applications; Second Law; Power and refrigeration cycles; Entropy calculations for ideal gases; Statistical Interpretation of Entropy; Property Relations for Single Phase Systems; Maxwell's Relations; Residual Property Calculations; Extension to Gas Mixtures. Vapor-Liquid Equilibria and Raoult's Law; Partial Molar Properties; Gibbs-Duhem Equation, Chemical potential and Fugacity; Ideal and non-ideal solutions; Excess Properties and activity coefficient models; Vapor-Liquid, Liquid-Liquid, Solid-Liquid and Chemical Reaction Equilibria; Introduction to Non-equilibrium Thermodynamics.

Text Book:

  1. J.M. Smith, Hendrick Van Ness, Michael Abbott and Mark Swihart, Introduction to Chemical Engineering Thermodynamics, 8th Ed., McGraw Hill Education, 2018.

Reference Books:

  1. Yunus A. Cengel, Michael A. Boles, Thermodynamics: An Engineering Approach, 8th Ed, McGraw Hill Education, 2015.
  2. S. I. Sandler, Chemical, Biochemical and Engineering Thermodynamics, 5th Ed., Wiley India, 2017.
  3. J. M. Prasusnitz, R. N. Lichtenthaler, and E. G. de Azevedo, Molecular Thermodynamics of Fluid-Phase Equilibria, 2nd Ed, Prentice Hall, Inc., 1986. By-.
  4. Y. V. C Rao, An Introduction to Thermodynamics, University Press, 2004.
  5. Milo D. Koretsky, Engineering and Chemical Thermodynamics, 2nd Edition, Wiley, 2012.